In any atom,which sub-shell will have the highest energy among the following?

According to which principle is the electronic configuration of nitrogen $1s^2 2s^2 2p_x^1 2p_y^1 2p_z^1$ and not $1s^2 2s^2 2p_x^2 2p_y^1 2p_z^0$?

The set of quantum numbers not applicable for an electron in an atom is

Pauli's exclusion principle states that

The quantum numbers of four electrons are given below:
$I. \ n = 4, l = 2, m_l = -2, m_s = -1/2$
$II. \ n = 3, l = 2, m_l = 1, m_s = +1/2$
$III. \ n = 4, l = 1, m_l = 0, m_s = +1/2$
$IV. \ n = 3, l = 1, m_l = 1, m_s = -1/2$
The correct order of their increasing energies will be:

Which of the following combinations of quantum numbers is allowed?