In Tollen's test for aldehyde,the overall number of electron$(s)$ transferred to the Tollen's reagent formula $[Ag(NH_{3})_{2}]^{+}$ per aldehyde group to form silver mirror is $......$. (Round off to the Nearest integer)

The reagent with which both aldehyde and acetone react easily is

Clemmensen's reduction will convert cyclohexanone into

Arrange the following compounds in the decreasing order of their reactivity towards nucleophilic addition reactions:
$(I) \, HCHO \, (II) \, CH_3CHO \, (III) \, CH_3COCH_3$

Aldehydes and ketones give pure addition reaction with:

Columns $1$,$2$,and $3$ contain starting materials,reaction conditions,and type of reactions,respectively.

$Column-1$	$Column-2$	$Column-3$
$(I)$ Toluene	$(i)$ $NaOH / Br_2$	$(P)$ Condensation
$(II)$ Acetophenone	$(ii)$ $Br_2 / h\nu$	$(Q)$ Carboxylation
$(III)$ Benzaldehyde	$(iii)$ $(CH_3CO)_2O / CH_3COOK$	$(R)$ Substitution
$(IV)$ Phenol	$(iv)$ $NaOH / CO_2$	$(S)$ Haloform

$(1)$ For the synthesis of benzoic acid,the only $CORRECT$ combination is
$[A] (III) (iv) (R)$ $[B] (IV) (ii) (P)$ $[C] (I) (iv) (Q)$ $[D] (II) (i) (S)$
$(2)$ The only $CORRECT$ combination in which the reaction proceeds through radical mechanism is
$[A] (I) (ii) (R)$ $[B] (II) (iii) (R)$ $[C] (III) (ii) (P)$ $[D] (IV) (i) (Q)$
$(3)$ The only $CORRECT$ combination that gives two different carboxylic acids is
$[A] (IV) (iii) (Q)$ $[B] (III) (iii) (P)$ $[C] (II) (iv) (R)$ $[D] (I) (i) (S)$