In which case is Raoult's law not applicable?

$A$ $0.0020 \ m$ aqueous solution of an ionic compound $[Co(NH_3)_5(NO_2)]Cl$ freezes at $-0.00732 \ ^oC.$ Number of moles of ions which $1 \ mol$ of ionic compound produces on being dissolved in water will be
$(K_f = 1.86 \ ^oC/m)$

Considering acetic acid dissociates in water,its dissociation constant is $6.25 \times 10^{-5}$. If $5 \ mL$ of acetic acid is dissolved in $1 \ L$ water,the solution will freeze at $-x \times 10^{-2} \ {}^{\circ}C$,provided pure water freezes at $0 \ {}^{\circ}C$.
$x = . . . . . . . . .$ (Nearest integer)
Given: $(K_{f})_{\text{water}} = 1.86 \ K \ kg \ mol^{-1}$.
Density of acetic acid is $1.2 \ g \ mL^{-1}$.
Molar mass of water $= 18 \ g \ mol^{-1}$.
Molar mass of acetic acid $= 60 \ g \ mol^{-1}$.
Density of water $= 1 \ g \ cm^{-3}$.
Acetic acid dissociates as:
$CH_3COOH \rightleftharpoons CH_3COO^{-} + H^{+}$

What is the expected value of $\Delta T_f$ for $1.25 \ m$ $CaCl_2$ solution if $1.25 \ m$ sucrose solution has $\Delta T_f$ value $x \ K$?

The depression in freezing point of a $NaCl$ solution is $6 \ K$. If $K_f = 1.86 \ K \ kg \ mol^{-1}$ for water,then the amount of $NaCl$ dissolved in $1 \ kg$ of water is ............. $mol$?

The freezing points of equimolar solutions of glucose,$KNO_3$ and $AlCl_3$ are in the order of: