The isoelectric point of alanine is $pH = 6$. At which $pH$ will the maximum concentration of the zwitterion of alanine be present?

  • A
    $pH > 6$
  • B
    $pH < 6$
  • C
    $pH = 6$
  • D
    $pH = 7$

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The substituents $R_1$ and $R_2$ for nine peptides are listed in the table given below. How many of these peptides are positively charged at $pH = 7.0$?
Peptide$R_1$$R_2$
$I$$H$$H$
$II$$H$$CH_3$
$III$$CH_2COOH$$H$
$IV$$CH_2CONH_2$$(CH_2)_4NH_2$
$V$$CH_2CONH_2$$CH_2CONH_2$
$VI$$(CH_2)_4NH_2$$(CH_2)_4NH_2$
$VII$$CH_2COOH$$CH_2CONH_2$
$VIII$$CH_2OH$$(CH_2)_4NH_2$
$IX$$(CH_2)_4NH_2$$CH_3$

Which of the following will not exist in zwitter ionic form at $pH = 7$?

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