Mark the correct statement.

For the kinetic study of the reaction of iodide ion with $H_{2}O_{2}$ at room temperature, which of the following statements are correct?
$(A)$ Always use freshly prepared starch solution.
$(B)$ Always keep the concentration of sodium thiosulphate solution less than that of $KI$ solution.
$(C)$ Record the time immediately after the appearance of blue colour.
$(D)$ Record the time immediately before the appearance of blue colour.
$(E)$ Always keep the concentration of sodium thiosulphate solution more than that of $KI$ solution.
Choose the correct answer from the options given below:

Given below are two statements:
Statement $I$: Sodium dichromate and potassium dichromate are classified as primary standards in titrimetric analysis.
Statement $II$: Phenolphthalein is a weak base, therefore it dissociates in acidic medium.

Prolonged heating is avoided during the preparation of ferrous ammonium sulphate to:

$CaCO_3$ (aqueous suspension) $\xrightarrow{AcOH}$ $\xrightarrow{Na_2C_2O_4 \text{ solution}}$
Which of the following observations is correct for the above experiment?

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$BaCrO_4 \downarrow + CH_3COOH \text{ (Excess)} \longrightarrow \text{No reaction}$