Match each coordination compound in List-$I$ with an appropriate pair of characteristics from List-$II$ and select the correct answer using the code given below the lists. $\{en = H_2NCH_2CH_2NH_2\}$,atomic numbers:$\{Ti = 22; Cr = 24; Co = 27; Pt = 78\}$
List-$I$
List-$II$
$P$. $[Cr(NH_3)_4Cl_2]Cl$
$1$. Paramagnetic and exhibits ionisation isomerism
$Q$. $[Ti(H_2O)_5Cl](NO_3)_2$
$2$. Diamagnetic and exhibits cis-trans isomerism
$R$. $[Pt(en)(NH_3)Cl]NO_3$
$3$. Paramagnetic and exhibits cis-trans isomerism
$S$. $[Co(NH_3)_4(NO_3)_2]NO_3$
$4$. Diamagnetic and exhibits ionisation isomerism
| List-$I$ | List-$II$ |
|---|---|
| $P$. $[Cr(NH_3)_4Cl_2]Cl$ | $1$. Paramagnetic and exhibits ionisation isomerism |
| $Q$. $[Ti(H_2O)_5Cl](NO_3)_2$ | $2$. Diamagnetic and exhibits cis-trans isomerism |
| $R$. $[Pt(en)(NH_3)Cl]NO_3$ | $3$. Paramagnetic and exhibits cis-trans isomerism |
| $S$. $[Co(NH_3)_4(NO_3)_2]NO_3$ | $4$. Diamagnetic and exhibits ionisation isomerism |
- A$P-4, Q-2, R-3, S-1$
- B$P-3, Q-1, R-4, S-2$
- C$P-2, Q-1, R-3, S-4$
- D$P-1, Q-3, R-4, S-2$
Explore More
Similar Questions
For the given aqueous reaction,which of the statement$(s)$ is (are) true?
$2KI + 2K_3[Fe(CN)_6] \xrightarrow{H_2SO_4} I_2 + 2K_4[Fe(CN)_6]$
$(A)$ The first reaction is a redox reaction.
$(B)$ White precipitate is $K_2Zn_3[Fe(CN)_6]_2$.
$(C)$ Addition of filtrate to starch solution gives blue colour.
$(D)$ White precipitate is soluble in $NaOH$ solution.
$2KI + 2K_3[Fe(CN)_6] \xrightarrow{H_2SO_4} I_2 + 2K_4[Fe(CN)_6]$
$(A)$ The first reaction is a redox reaction.
$(B)$ White precipitate is $K_2Zn_3[Fe(CN)_6]_2$.
$(C)$ Addition of filtrate to starch solution gives blue colour.
$(D)$ White precipitate is soluble in $NaOH$ solution.
Magnetic moment (spin only) of an octahedral complex having $CFSE = -0.8 \Delta_0$ and surrounded by weak field ligands can be
Given below are two statements.
Statement $I$: In $CuSO_{4} \cdot 5H_{2}O$,$Cu-O$ bonds are present.
Statement $II$: In $CuSO_{4} \cdot 5H_{2}O$,ligands coordinating with $Cu(II)$ ion are $O$- and $S$-based ligands.
In the light of the above statements,choose the correct answer from the options given below.
Statement $I$: In $CuSO_{4} \cdot 5H_{2}O$,$Cu-O$ bonds are present.
Statement $II$: In $CuSO_{4} \cdot 5H_{2}O$,ligands coordinating with $Cu(II)$ ion are $O$- and $S$-based ligands.
In the light of the above statements,choose the correct answer from the options given below.
Some statements are given below $-$
$(a)$ Coordination compounds $[Pt(NH_3)_3(NCS)]$ and $[Pt(NH_3)_3(SCN)]$ are examples of linkage isomerism.
$(b)$ In the coordination compound $K_4[Ni(CN)_4]$, the oxidation state of nickel is zero.
$(c)$ The hybridization, shape and magnetic moment of $K_3[Cu(CN)_4]$ are respectively $dsp^2$, square planar, $1.73 \ B.M.$
$(d)$ $[Cr(NCS)(NH_3)_5][ZnCl_4]$ exhibits only linkage isomerism.
$(a)$ Coordination compounds $[Pt(NH_3)_3(NCS)]$ and $[Pt(NH_3)_3(SCN)]$ are examples of linkage isomerism.
$(b)$ In the coordination compound $K_4[Ni(CN)_4]$, the oxidation state of nickel is zero.
$(c)$ The hybridization, shape and magnetic moment of $K_3[Cu(CN)_4]$ are respectively $dsp^2$, square planar, $1.73 \ B.M.$
$(d)$ $[Cr(NCS)(NH_3)_5][ZnCl_4]$ exhibits only linkage isomerism.
Medium
View SolutionIn which of the following complexes is the pairing of $(n-1)d$ electrons $NOT$ present in the presence of strong field ligands $(SFL)$?
Difficult
View SolutionVedclass Products
For Students
Vedclass Test Series
Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.
Start Free TrialFor Teachers
Exam Paper Generator
Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.
Try FreeFor Institutes
Online Exam Module
Live online exams with unlimited students, 360° analytics & white-label branding.
See Demo