Match each of the compounds given in Column $I$ with the reaction$(s)$ that they can undergo,given in Column $II$.
| Column $I$ | Column $II$ |
| :--- | :--- |
| $(A)$ $3-$bromobenzofuran derivative | $(p)$ Nucleophilic substitution |
| $(B)$ Benzyl alcohol | $(q)$ Elimination |
| $(C)$ Salicylaldehyde | $(r)$ Nucleophilic addition |
| $(D)$ $1-$bromo$-2-$nitrobenzene | $(s)$ Esterification with acetic anhydride |
| | $(t)$ Dehydrogenation |

  • A
    $A-p, q, t; B-p, s, t; C-r, s; D-p$
  • B
    $A-p, q, t; B-p, s, t; C-r, s; D-p$
  • C
    $A-p, q, s; B-p, s, q; C-r, q; D-s$
  • D
    $A-p, q, t; B-p, s, t; C-r, s; D-p$

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Match the reactions given in Column-$I$ with the names of the products and reactions given in Column-$II$.
Column-$I$ (Reaction) Column-$II$ (Product and Reaction Name)
$A$. Phenol $+$ dilute $HNO_3$ $i$. Mononitrophenol,Nitration
$B$. Phenol $+$ Bromine water $ii$. $2,4,6$-Tribromophenol,Bromination
$C$. Phenol $+$ $Na_2Cr_2O_7/H_2SO_4$ $iii$. Benzoquinone,Oxidation
$D$. Sodium phenoxide $+$ $CO_2$ followed by $H^+$ $iv$. Salicylic acid,Kolbe reaction

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$(i)$ Draw the structures of all isomeric alcohols of molecular formula $C_5H_{12}O$ and give their $IUPAC$ names.
$(ii)$ Classify the isomers of alcohols in question $(i)$ as primary,secondary and tertiary alcohols.

The reaction of elemental sulphur with a Grignard reagent followed by acidification leads to the formation of:

Match the reactants in Column-$I$ with the products formed in Column-$II$.
Column-$I$ (Reactants) Column-$II$ (Products)
$A$. Cumene $+ O_2$ $i$. Phenol
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$C$. Chlorobenzene $+ NaOH \xrightarrow{623 \ K, 300 \ atm}$ $iii$. Cumene hydroperoxide
$D$. $2$-Methylbutanal $\xrightarrow{NaBH_4}$ $iv$. Sodium phenoxide

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