Match List-$I$ with List-$II$.

$LIST$-$I$ (Precipitating reagent and conditions)	$LIST$-$II$ (Cation)
$A$. $NH_4Cl + NH_4OH$	$I$. $Mn^{2+}$
$B$. $NH_4OH + (NH_4)_2CO_3$	$II$. $Pb^{2+}$
$C$. $NH_4OH + NH_4Cl + H_2S$ gas	$III$. $Al^{3+}$
$D$. Dilute $HCl$	$IV$. $Sr^{2+}$

Choose the correct answer from the options given below:

Upon treatment with ammoniacal $H_2S$,the metal ion that precipitates as a sulfide is

Which of the following is sparingly soluble in cold water and fairly soluble in hot water?

$A$ salt '$A$' which gives a green flame with a Bunsen burner,on reaction with dil. $H_2SO_4$ produces gas $(2)$ and white turbidity $(Z)$. The saturated solution of gas $(2)$ on reaction with $H_2S$ gas produces '$Z$'. Then select the $CORRECT$ statement.

Which reagent is used in the qualitative analysis of Group $IV$ cations?

An aqueous solution of a mixture of two inorganic salts,when treated with dilute $HCl$,gave a precipitate $(P)$ and a filtrate $(Q)$. The precipitate $P$ was found to dissolve in hot water. The filtrate $(Q)$ remained unchanged when treated with $H_2S$ in a dilute mineral acid medium. However,it gave a precipitate $(R)$ with $H_2S$ in an ammoniacal medium. The precipitate $R$ gave a coloured solution $(S)$ when treated with $H_2O_2$ in an aqueous $NaOH$ medium.
$1.$ The precipitate $P$ contains
$(A)$ $Pb^{2+}$ $(B)$ $Hg_2^{2+}$ $(C)$ $Ag^{+}$ $(D)$ $Hg^{2+}$
$2.$ The coloured solution $S$ contains
$(A)$ $Fe_2(SO_4)_3$ $(B)$ $CuSO_4$ $(C)$ $ZnSO_4$ $(D)$ $Na_2CrO_4$