Match the following based on valence bond theory $(VBT)$.
Hybridisation Geometry Complex structure $(A) \ sp^3$ $(i) \ \text{Square planar}$ $(p) \ [Fe(CN)_6]^{3-}$ $(B) \ d^2sp^3$ $(ii) \ \text{Tetrahedral}$ $(q) \ [ZnCl_4]^{2-}$ $(C) \ dsp^2$ $(iii) \ \text{Octahedral}$ $(r) \ [Ni(NH_3)_4]^{2+}$ - $(iv) \ \text{Linear}$ $(s) \ [Ag(CN)_2]^-$
| Hybridisation | Geometry | Complex structure |
|---|---|---|
| $(A) \ sp^3$ | $(i) \ \text{Square planar}$ | $(p) \ [Fe(CN)_6]^{3-}$ |
| $(B) \ d^2sp^3$ | $(ii) \ \text{Tetrahedral}$ | $(q) \ [ZnCl_4]^{2-}$ |
| $(C) \ dsp^2$ | $(iii) \ \text{Octahedral}$ | $(r) \ [Ni(NH_3)_4]^{2+}$ |
| - | $(iv) \ \text{Linear}$ | $(s) \ [Ag(CN)_2]^-$ |
- A$(A-ii-q), (B-iii-p), (C-i-r)$
- B$(A-ii-q), (B-iii-r), (C-i-s)$
- C$(A-i-q), (B-iii-p), (C-ii-r)$
- D$(A-ii-r), (B-iii-s), (C-i-q)$
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Similar Questions
For which of the following $d^n$ configurations of octahedral complexes,can they $NOT$ exist in both high spin and low spin forms?
$(I)$ $d^3$,$(II)$ $d^5$,$(III)$ $d^6$,$(IV)$ $d^8$
$(I)$ $d^3$,$(II)$ $d^5$,$(III)$ $d^6$,$(IV)$ $d^8$
Which of the following complexes exhibits $sp^{3}d$ hybridization?
Medium
View SolutionWhich of the following statements is correct regarding the $[Fe(CN)_6]^{4-}$ complex?
Difficult
View SolutionThe type of hybridization involved in the metal ion of the $[Ni(H_2O)_6]^{2+}$ complex is:
Medium
View SolutionMatch the hybridisation in Column $I$ with the complexes in Column $II$. The options represent the matches for $(A), (B), (C), (D)$ respectively.
Column $I$ Column $II$ $(A)$ $sp^3$ $(i)$ $[Co(NH_3)_6]^{3+}$ $(B)$ $dsp^2$ $(ii)$ $[Ni(CO)_4]$ $(C)$ $sp^3d^2$ $(iii)$ $[Pt(NH_3)_2Cl_2]$ $(D)$ $d^2sp^3$ $(iv)$ $[CoF_6]^{3-}$ $(v)$ $[Fe(CO)_5]$
| Column $I$ | Column $II$ |
|---|---|
| $(A)$ $sp^3$ | $(i)$ $[Co(NH_3)_6]^{3+}$ |
| $(B)$ $dsp^2$ | $(ii)$ $[Ni(CO)_4]$ |
| $(C)$ $sp^3d^2$ | $(iii)$ $[Pt(NH_3)_2Cl_2]$ |
| $(D)$ $d^2sp^3$ | $(iv)$ $[CoF_6]^{3-}$ |
| $(v)$ $[Fe(CO)_5]$ |
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