Match the List-$I$ with List-$II$:
List-$I$ (Reagent) List-$II$ (Functional Group detected)
$A$. Sodium bicarbonate solution $I$. Double bond/unsaturation
$B$. Neutral ferric chloride $II$. Carboxylic acid
$C$. Ceric ammonium nitrate $III$. Phenolic $-OH$
$D$. Alkaline $KMnO_4$ $IV$. Alcoholic $-OH$

Choose the correct answer from the options given below:

  • A
    $A-II, B-III, C-IV, D-I$
  • B
    $A-II, B-III, C-I, D-IV$
  • C
    $A-III, B-II, C-IV, D-I$
  • D
    $A-II, B-IV, C-III, D-I$

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Acidified sodium fusion extract on addition of ferric chloride solution gives blood red colouration,which confirms the presence of:

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Column $I$ Column $II$
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$C. HO-C_6H_4-NH_3^+Cl^-$ $r. \text{Gives white precipitate with } AgNO_3$
$D. (NO_2)_2C_6H_3-NH-NH_3^+Br^-$ $s. \text{Reacts with aldehydes to form the corresponding hydrazone derivative}$

In the detection of halogens,what is formed by adding $AgNO_3$? What is its colour?

In the Lassaigne's test for the detection of sulfur,which substance is responsible for the formation of black precipitates?

What happens to the halogen when $AgNO_3$ is added to the Lassaigne solution acidified with $HNO_3$?

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