The Nernst equation is related to:

  • A
    The electrode potential and concentration of ions in the solution
  • B
    Equilibrium constant and concentration of ions
  • C
    Free energy change and $E$.$M$.$F$. of the cell
  • D
    None of these

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Which of the following will increase the voltage of the cell represented by the equation
$Cu_{(s)} + 2Ag^{+}_{(aq)} \to Cu^{2+}_{(aq)} + 2Ag_{(s)}$

$Cu_{(s)} | Cu^{+2}(aq, 10^{-3} M) || Ag^{+}(aq, 10^{-5} M) | Ag_{(s)}$
If $E^{o}_{Cu^{+2}/Cu} = +0.34 \ V$
$E^{o}_{Ag^{+}/Ag} = +0.80 \ V$
$E_{cell}$ will be

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What must be the concentration of $Ag^{+}$ in an aqueous solution containing $Cu^{2+} = 1.0 \ M$ so that both the metals can be deposited on the cathode simultaneously? Given that $E^0_{Cu^{2+}/Cu} = 0.34 \ V$ and $E^0_{Ag^{+}/Ag} = 0.812 \ V$ at $T = 298 \ K$.

For a cell,$Cu_{(s)} \mid Cu^{2+}(0.001\,M) \mid\mid Ag^{+}(0.01\,M) \mid Ag_{(s)}$,the cell potential is found to be $0.43\,V$ at $298\,K$. The magnitude of standard electrode potential for $Cu^{2+}/Cu$ is $......... \times 10^{-2}\,V$. $[\text{Given}: E^{\Theta}_{Ag^{+}/Ag} = 0.80\,V \text{ and } \frac{2.303RT}{F} = 0.06\,V]$

Calculate the equilibrium constant for the cell reaction at $298 \ K$: $Cu_{(s)} + 2Ag^{+}_{(aq)} \rightarrow Cu^{2+}_{(aq)} + 2Ag_{(s)}$,given $E^{0}_{cell} = 0.46 \ V$.

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