Nitroglycerine $(MW = 227.1)$ detonates according to the following equation:
$2 C_{3}H_{5}(NO_{3})_{3(l)} \longrightarrow 3 N_{2(g)} + \frac{1}{2} O_{2(g)} + 6 CO_{2(g)} + 5 H_{2}O_{(g)}$
The standard molar enthalpies of formation,$\Delta H_{f}^{\circ}$ for all the compounds are given below:
$\Delta H_{f}^{\circ}[C_{3}H_{5}(NO_{3})_{3}] = -364 \, kJ/mol$
$\Delta H_{f}^{\circ}[CO_{2(g)}] = -393.5 \, kJ/mol$
$\Delta H_{f}^{\circ}[H_{2}O_{(g)}] = -241.8 \, kJ/mol$
$\Delta H_{f}^{\circ}[N_{2(g)}] = 0 \, kJ/mol$
$\Delta H_{f}^{\circ}[O_{2(g)}] = 0 \, kJ/mol$
The enthalpy change when $10 \, g$ of nitroglycerine is detonated is $..... \, kJ$.
$2 C_{3}H_{5}(NO_{3})_{3(l)} \longrightarrow 3 N_{2(g)} + \frac{1}{2} O_{2(g)} + 6 CO_{2(g)} + 5 H_{2}O_{(g)}$
The standard molar enthalpies of formation,$\Delta H_{f}^{\circ}$ for all the compounds are given below:
$\Delta H_{f}^{\circ}[C_{3}H_{5}(NO_{3})_{3}] = -364 \, kJ/mol$
$\Delta H_{f}^{\circ}[CO_{2(g)}] = -393.5 \, kJ/mol$
$\Delta H_{f}^{\circ}[H_{2}O_{(g)}] = -241.8 \, kJ/mol$
$\Delta H_{f}^{\circ}[N_{2(g)}] = 0 \, kJ/mol$
$\Delta H_{f}^{\circ}[O_{2(g)}] = 0 \, kJ/mol$
The enthalpy change when $10 \, g$ of nitroglycerine is detonated is $..... \, kJ$.
- A$-100.5$
- B$-62.5$
- C$-80.3$
- D$-74.9$
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Given:
$(I) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}; \Delta H^o_{298\ K} = -285.9 \ kJ \ mol^{-1}$
$(II) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(g)}; \Delta H^o_{298\ K} = -241.8 \ kJ \ mol^{-1}$
The molar enthalpy of vaporisation of water will be $kJ \ mol^{-1}$.
$(I) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(l)}; \Delta H^o_{298\ K} = -285.9 \ kJ \ mol^{-1}$
$(II) \ H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(g)}; \Delta H^o_{298\ K} = -241.8 \ kJ \ mol^{-1}$
The molar enthalpy of vaporisation of water will be $kJ \ mol^{-1}$.
DifficultJEE MAIN 2013
View SolutionCalculate the bond enthalpy of the $H-Cl$ bond from the following reaction:
$H_{2(g)} + Cl_{2(g)} \rightarrow 2 HCl_{(g)}$,$\Delta_{r} H^{\circ} = -185 \ kJ \ mol^{-1}$
(Given bond enthalpies of $H-H$ and $Cl-Cl$ bonds are $435.0 \ kJ \ mol^{-1}$ and $244 \ kJ \ mol^{-1}$ respectively.)
$H_{2(g)} + Cl_{2(g)} \rightarrow 2 HCl_{(g)}$,$\Delta_{r} H^{\circ} = -185 \ kJ \ mol^{-1}$
(Given bond enthalpies of $H-H$ and $Cl-Cl$ bonds are $435.0 \ kJ \ mol^{-1}$ and $244 \ kJ \ mol^{-1}$ respectively.)
If the value of $\Delta H$ in a reaction is positive,then the reaction is called
Easy
View SolutionHess's law is based on
Easy
View SolutionThe bond dissociation enthalpy of $H_{2(g)}$ and $N_{2(g)}$ are $436 \ kJ \ mol^{-1}$ and $940 \ kJ \ mol^{-1}$ respectively,and the enthalpy of formation of $NH_{3(g)}$ is $-45 \ kJ \ mol^{-1}$. The enthalpy of atomisation of $NH_{3(g)}$ is ..... $kJ \ mol^{-1}$.
Difficult
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