On increasing the number density of a gas in a vessel,the mean free path of the gas:

The internal energy of real gases is determined by which of the following?

The mean free path of molecules of a gas (radius $r$) is inversely proportional to

There are two identical chambers,completely thermally insulated from surroundings. Both chambers have a partition wall dividing the chambers into two compartments. Compartment $1$ is filled with an ideal gas and Compartment $3$ is filled with a real gas. Compartments $2$ and $4$ are vacuum. $A$ small hole (orifice) is made in the partition walls and the gases are allowed to expand into the vacuum.
Statement $-1$: No change in the temperature of the gas takes place when an ideal gas expands in a vacuum. However,the temperature of a real gas goes down (cooling) when it expands in a vacuum.
Statement $-2$: The internal energy of an ideal gas is only kinetic. The internal energy of a real gas is kinetic as well as potential.

If $n$ is the number density and $d$ is the diameter of the molecule,then the average distance covered by a molecule between two successive collisions (i.e. mean free path) is represented by :

The mean free path of electrons in a metal is $4 \times 10^{-8} \;m$. The electric field which can give on an average $2 \;eV$ energy to an electron in the metal will be in units of $V/m$.