One of the assumptions of the kinetic theory of gases is that there is no force of attraction between the molecules of a gas. State and explain the evidence that shows that this assumption is not applicable for real gases.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The kinetic theory of gases assumes that gas molecules do not exert any force of attraction on each other. However,this assumption fails for real gases because they can be liquefied by cooling and applying high pressure.
If there were no intermolecular forces of attraction,it would be impossible to liquefy a gas,as the molecules would not come together to form a liquid phase. The existence of intermolecular forces,such as van der Waals forces or hydrogen bonding (e.g.,in $HF$),allows molecules to aggregate,leading to liquefaction.
Evidence: The process of liquefaction of gases like $NH_3$,$CO_2$,and $Cl_2$ under high pressure and low temperature provides direct evidence that intermolecular forces of attraction exist in real gases.

Explore More

Similar Questions

Van der Waals's equation of state is obeyed by real gases. For $n$ moles of a real gas,the expression will be :-

If $Z$ is a compressibility factor,the van der Waals equation at low pressure can be written as:

Consider the following table:
Gas $a / (kPa \cdot dm^6 \cdot mol^{-2})$ $b / (dm^3 \cdot mol^{-1})$
$A$ $642.32$ $0.05196$
$B$ $155.21$ $0.04136$
$C$ $431.91$ $0.05196$
$D$ $155.21$ $0.4382$

$a$ and $b$ are van der Waals constants. The correct statement about the gases is:

The term that accounts for intermolecular force in Van der Waals equation for non-ideal gas is

The units of constant $a$ in the Van der Waals equation are:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo