Which of the following pairs of compounds is planar?

  • A
    $[Ni(CN)_4]^{3-}, [PtCl_4]^{2-}$
  • B
    $[NiCl_4]^{2-}, [Ni(CN)_4]^{2-}$
  • C
    $[Ni(CN)_4]^{2-}, [Rh(CO)_2(PPh_3)_2]^+$
  • D
    $[PtCl_4]^{2-}, [Ni(CO)_4]$

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The metal $Ni$ $(Z = 28)$ combines with a unidentate ligand $X^-$ to form a paramagnetic complex $[NiX_4]^{2-}$. What are its geometry and the number of unpaired electrons in $Ni$?

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Match the List-$I$ with List-$II$:
List-$I$ (Complex/Species) List-$II$ (Shape and magnetic moment)
$A$. $[Ni(CO)_4]$ $I$. Tetrahedral,$2.8 \ BM$
$B$. $[Ni(CN)_4]^{2-}$ $II$. Square planar,$0 \ BM$
$C$. $[NiCl_4]^{2-}$ $III$. Tetrahedral,$0 \ BM$
$D$. $[MnBr_4]^{2-}$ $IV$. Tetrahedral,$5.9 \ BM$

Choose the correct answer from the options given below:

The ammine complexes of metal ions $Cu^{2+}$,$Ni^{2+}$ and $Zn^{2+}$ have shapes respectively:

For the complexes showing the square pyramidal structure,the $d-$orbital involved in the hybridisation is

In aqueous solution,$[Co(H_2O)_6]^{2+} (X)$ reacts with molecular oxygen in the presence of excess liquor $NH_3$ to give a new complex $Y$. The number of unpaired electrons in $X$ and $Y$ are,respectively:

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