Phosphine is prepared by the reaction of

Which compound is related to Haber's process?

Given below are two statements:
Statement $I$: The $N-N$ single bond is weaker and longer than the $P-P$ single bond.
Statement $II$: Compounds of group $15$ elements in $+3$ oxidation state readily undergo disproportionation reactions.
In the light of the above statements,choose the correct answer from the options given below:

Lapis lazuli is

Two oxides of nitrogen,$NO$ and $NO_2$ are allowed to react together at $243 \ K$ to form a coloured compound of nitrogen $(X)$. When compound $(X)$ reacts with water,it yields another compound of nitrogen $(Y)$. The shape of the anion of $(Y)$ molecule is:

Sodium nitrite with hydrochloric acid gives water along with two nitrogen oxides. They are