Phosphorus pentachloride $(PCl_{5})$:
- Aon hydrolysis gives an oxo-acid of phosphorus which is tribasic
- Bon hydrolysis gives an oxo-acid of phosphorus which is a good reducing agent
- Chas all the five equivalent bonds
- Dexists as an ionic solid in which cation has octahedral structure and anion has tetrahedral structure
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Similar Questions
Match the following:
Compound Nature $i$. $PbO_2$ $a$. Acidic $ii$. $Sb_2O_3$ $b$. Basic $iii$. $GeO_2$ $c$. Amphoteric
| Compound | Nature |
|---|---|
| $i$. $PbO_2$ | $a$. Acidic |
| $ii$. $Sb_2O_3$ | $b$. Basic |
| $iii$. $GeO_2$ | $c$. Amphoteric |
Easy
View SolutionMatch the reactions (in the given stoichiometry of the reactants) in List-$I$ with one of their products given in List-$II$ and choose the correct option.
List-$I$ List-$II$ $A. P_2 O_3 + 3 H_2 O \rightarrow$ $1. P(O)(OCH_3)Cl_2$ $B. P_4 + 3 NaOH + 3 H_2 O \rightarrow$ $2. H_3 PO_3$ $C. PCl_5 + CH_3 COOH \rightarrow$ $3. PH_3$ $D. H_3 PO_2 + 2 H_2 O + 4 AgNO_3 \rightarrow$ $4. CH_3 COCl$ $5. H_3 PO_4$
| List-$I$ | List-$II$ |
| $A. P_2 O_3 + 3 H_2 O \rightarrow$ | $1. P(O)(OCH_3)Cl_2$ |
| $B. P_4 + 3 NaOH + 3 H_2 O \rightarrow$ | $2. H_3 PO_3$ |
| $C. PCl_5 + CH_3 COOH \rightarrow$ | $3. PH_3$ |
| $D. H_3 PO_2 + 2 H_2 O + 4 AgNO_3 \rightarrow$ | $4. CH_3 COCl$ |
| $5. H_3 PO_4$ |
Ammonia is liberated in the reaction of
Difficult
View SolutionIn the following reaction,assign the correct option for the underlined atom in the product of complete hydrolysis at $R.T.$:
$\underline{N}_2O_3 + H_2O \longrightarrow 2HNO_2$
$\underline{N}_2O_3 + H_2O \longrightarrow 2HNO_2$
Difficult
View SolutionGive the preparation of phosphine $(PH_{3})$. State the physical and chemical properties of phosphine $(PH_{3})$. State the uses of phosphine.
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