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Acid hydrolysis of $X$ yields two different organic compounds. Which one of the following is $X$?

The final product $(III)$ obtained in the reaction sequence is:
$CH_3-CH_2-COOH$ $\xrightarrow{PCl_3} I$ $\xrightarrow{C_6H_6/AlCl_3} II$ $\xrightarrow{NH_2-NH_2/\text{base/heat}} III$

Arrange the following compounds in the increasing order of their $pK_a$ values:
$I.$ Phenol
$II.$ $p$-Nitrophenol
$III.$ Ethanol
$IV.$ $p$-Nitrobenzoic acid

Identify the correct decreasing order of boiling points for the following organic compounds.

Write the chemical reactions for the following conversions:
$1.$ $1$-Bromopropane to Propan-$1$-ol and Propan-$2$-ol
$2.$ Ethanoic acid to Methanol

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