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Question

(C) The reaction of phenol with acetyl chloride $(CH_3COCl)$ in the presence of a base forms phenyl acetate as product $(P)$.This is an esterification

Vedclass · Accepted Answer

$p$-Hydroxyacetophenone

Vedclass · Answer

(C) The reaction of phenol with acetyl chloride $(CH_3COCl)$ in the presence of a base forms phenyl acetate as product $(P)$.This is an esterification reaction.When phenyl acetate $(P)$ is heated with anhydrous $AlCl_3$,it undergoes Fries rearrangement to form a mixture of $o$-hydroxyacetophenone and $p$-hydroxyacetophenone.$p$-Hydroxyacetophenone is the major product $(Q)$ at higher temperatures.Therefore,the correct option is $(C)$.

Product $(Q)$ in this reaction is

Similar Questions

The increasing order of $pK_{a}$ for the following phenols is:
$1$. $2, 4-$Dinitrophenol
$2$. $4-$Nitrophenol
$3$. $2, 4, 5-$Trimethylphenol
$4$. Phenol
$5$. $3-$Chlorophenol

Which of the following is the major product,when $p$-cresol is treated with zinc dust?

Assertion: Phenol undergoes Kolbe reaction,ethanol does not.
Reason: Phenoxide ion is more basic than ethoxide ion.

Out of $o-$nitrophenol and $o-$cresol,which is more acidic?

Characteristics of the above reaction is:

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