Propene when heated with chlorine at about 50 | vedclass

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Question

(A) The reaction of propene with chlorine at high temperature $(500 \, ^oC)$ is an example of allylic substitution. $CH_3-CH=CH_2 + Cl_2 \xrightarrow{

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$Cl-CH_2-CH=CH_2$

Vedclass · Answer

(A) The reaction of propene with chlorine at high temperature $(500 \, ^oC)$ is an example of allylic substitution. $CH_3-CH=CH_2 + Cl_2 \xrightarrow{500 \, ^oC} Cl-CH_2-CH=CH_2 + HCl$ In this reaction,the chlorine atom replaces a hydrogen atom at the allylic position (the carbon atom adjacent to the double bond) rather than undergoing addition across the double bond.

Propene when heated with chlorine at about $500 \, ^oC$ forms

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