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Explain:
$(i)$ Zone refining
$(ii)$ Column chromatography.

Difficult
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The electrolyte solution in the electrolytic refining of lead contains:

Match the refining methods (Column $I$) with metals (Column $II$).
Column $I$ (Refining methods) Column $II$ (Metals)
$(I)$ Liquation $(a)$ $Zr$
$(II)$ Zone refining $(b)$ $Ni$
$(III)$ Mond process $(c)$ $Sn$
$(IV)$ Van Arkel Method $(d)$ $Ga$

The Van-Arkel process and Mond's process are used for the refining of which of the following metals,respectively?

In the zone-refining method,the molten zone:

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