Select the correct statement:

  • A
    Pure chloroform gives a precipitate with $aq. AgNO_3$.
  • B
    Chloroform is used as an analgesic.
  • C
    Iodoform is an anesthetic.
  • D
    $Ph-CO-CH_2-CO-Ph$ with $NaOH + I_2$ gives a yellow precipitate.

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$A$ (organic compound) $+ O_2 \to X + Y + Z$. Compound $(A)$ in pure form does not give a precipitate with $AgNO_3$ solution. $A$ mixture containing $70\%$ of $(A)$ and $30\%$ of ether is used as an anaesthetic. Compound $(X)$ and $(Y)$ are oxides while $(Z)$ is a pungent smelling gas. $(X)$ is a neutral oxide which turns cobalt chloride paper pink. Compound $(Y)$ turns lime water milky and produces an acidic solution with water. Compounds $(A), (X), (Y)$ and $(Z)$ respectively will be:

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Which of the following products can be obtained from the above reaction?

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How will you bring about the following conversions?
$(i)$ Ethanol to but$-1-$yne
$(ii)$ Ethane to bromoethene
$(iii)$ Propene to $1-$nitropropane
$(iv)$ Toluene to benzyl alcohol
$(v)$ Propene to propyne
$(vi)$ Ethanol to ethyl fluoride
$(vii)$ Bromomethane to propanone
$(viii)$ But$-1-$ene to but$-2-$ene
$(ix)$ $1-$Chlorobutane to $n-$octane
$(x)$ Benzene to biphenyl.

When $32.25 \ g$ of ethyl chloride undergoes dehydrohalogenation,it yields $50\%$ of the theoretical alkene product. What is the mass of the product obtained in $g$? (Atomic mass: $Cl = 35.5, C = 12, H = 1$)

Match List-$I$ with List-$II$:
| List-$I$ | List-$II$ |
| :--- | :--- |
| $A$. $C_6H_5Cl + CH_3Cl + 2Na \rightarrow C_6H_5CH_3 + 2NaCl$ | $I$. Wurtz-Fitting reaction |
| $B$. $2C_6H_5Cl + 2Na \rightarrow C_6H_5-C_6H_5 + 2NaCl$ | $II$. Fitting reaction |
| $C$. $C_6H_5N_2^+Cl^- \xrightarrow{Cu_2Cl_2} C_6H_5Cl + N_2$ | $III$. Sandmeyer reaction |
| $D$. $C_2H_5Cl + NaI \rightarrow C_2H_5I + NaCl$ | $IV$. Finkelstein reaction |

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