Select the compound which on treatment with nitrous acid liberates nitrogen.

Identify the final product $Z$ in the following reaction sequence:

$A$ primary amine can be converted to an alcohol by the action of

The correct statements of the following are:
$A$. Aniline forms a stable benzene diazonium chloride at $285 \ K$.
$B$. $N$-Phenylethanamide is less reactive towards nitration than aniline.
$C$. $p-CH_3C_6H_4COCl$ is Hinsberg reagent.

Starting from propanoic acid,the following reactions were carried out: $CH_3-CH_2-COOH$ $\xrightarrow{SOCl_2} X$ $\xrightarrow{NH_3} Y$ $\xrightarrow{Br_2 + KOH} Z$. What is the compound $Z$?

Assertion $(A)$: $-NH_2$ group of aniline is ortho,para directing in electrophilic substitutions.
Reason $(R)$: $-NH_2$ group stabilises the arenium ion formed by the ortho,para attack of the electrophile.
The correct answer is