Sodium fusion extract of aniline,when heated with ferrous sulphate solution and then acidified with concentrated $H_2SO_4$,forms which of the following complexes?

  • A
    $\left[Fe(CN)_6\right]^{4-}$
  • B
    $Fe_4\left[Fe(CN)_6\right]_3 \cdot x H_2O$
  • C
    $[Fe(SCN)]^{2+}$
  • D
    $\left[Fe(CN)_5NOS\right]^{4-}$

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Which of the following nitrogen-containing compounds does not give Lassaigne's test?

In the preparation of sodium fusion extract,the purpose of fusing organic compound with a piece of sodium metal is to

Match column $-I$ and column $-II$ with the correct relation:
Column $-I$ Column $-II$
$(i).$ Lassaigne's test $(a).$ By sodium peroxide
$(ii).$ Test for nitrogen $(b).$ Acidify with acetic acid
$(iii).$ Test for sulphur $(c).$ Acidify with conc. sulphuric acid
$(iv).$ Test for phosphorus $(d).$ Fusion with sodium

When sodium fusion extract of an organic compound is boiled with iron$(II)$ sulphate solution followed by addition of concentrated $H_2SO_4$,it gives a Prussian blue colour. This confirms the presence of which element?

Given below are two statements :
Statement $I$ : In Lassaigne's Test,when both nitrogen and sulphur are present in an organic compound,sodium thiocyanate is formed.
Statement $II$ : If both nitrogen and sulphur are present in an organic compound,then the excess of sodium used in sodium fusion will decompose the sodium thiocyanate formed to give $NaCN$ and $Na_{2}S$.
In the light of the above statements,choose the most appropriate answer from the options given below.

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