Standard enthalpy of vapourisation for $CCl_4$ is $30.5 \ kJ \ mol^{-1}$. Heat required for vapourisation of $284 \ g$ of $CCl_4$ at constant temperature is . . . . . . $kJ$. (Given molar mass in $g \ mol^{-1} ; C=12, Cl=35.5$ )

  • A
    $78$
  • B
    $12$
  • C
    $46$
  • D
    $56$

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If $1 \ mole$ of aqueous nitric acid is formed,calculate the total heat released based on the following reactions:
Reaction$\Delta H \ (kJ)$
$(i) \ 4NH_{3(g)} + 5O_{2(g)} \to 4NO_{(g)} + 6H_2O_{(l)}$$-904$
$(ii) \ 2NO_{(g)} + O_{2(g)} \to 2NO_{2(g)}$$-112$
$(iii) \ 3NO_{2(g)} + H_2O_{(l)} \to 2HNO_{3(aq)} + NO_{(g)}$$-140$

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$A$ sample of $n$-octane $(1.14 \ g)$ was completely burnt in excess of oxygen in a bomb calorimeter,whose heat capacity is $5 \ kJ \ K^{-1}$. As a result of the combustion reaction,the temperature of the calorimeter increased by $5 \ K$. The magnitude of the heat of combustion of octane at constant volume is $.......... \ kJ \ mol^{-1}$ (nearest integer).

Assertion : The increase in internal energy $(\Delta E)$ for the vaporization of one mole of water at $1 \ atm$ and $373 \ K$ is zero.
Reason : For all isothermal processes,$\Delta E = 0$.

$A$ mixture of $H_2$ and a sufficient quantity of air at $25\,^{\circ}C$ and $1\ atm$ pressure undergoes complete combustion in a closed rigid adiabatic container,leaving behind $H_2O_{(g)}$ and $N_{2(g)}$. If air is a mixture of $80\% N_2$ and $20\% O_2$ by volume and $C_{P(N_2)}$ and $C_{P(H_2O)g}$ are $7.0$ and $8.0\ cal\ deg^{-1}\ mol^{-1}$ respectively,what will be the maximum temperature attained? (Given that: $(\Delta H^o_f)_{H_2O_{(g)}} = -56.0\ kcal/mol$ and it is independent of temperature)...... $K$

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The enthalpy of formation of $H_2O$ is $-68 \ k.cal/mol$. Calculate the enthalpy of formation of $OH^-$. Given that the enthalpy of neutralization of $H^+$ and $OH^-$ is $-13.7 \ k.cal/mol$.

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