Statement $I :$ Leaching of gold with cyanide ion in absence of air $/$ $O_2$ leads to cyano complex of $Au(III)$.
Statement $II :$ Zinc is oxidized during the displacement reaction carried out for gold extraction.
In the light of the above statements,choose the correct answer from the options given below.

  • A
    Both Statement $I$ and Statement $II$ are correct
  • B
    Both Statement $I$ and Statement $II$ are incorrect
  • C
    Statement $I$ is correct but Statement $II$ is incorrect
  • D
    Statement $I$ is incorrect but Statement $II$ is correct

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Tin is obtained from cassiterite by reduction with coke. Use the data given below to determine the minimum temperature (in $K$) at which the reduction of cassiterite by coke would take place.
At $298 \ K$: $\Delta_{f}H^{\circ}(SnO_{2(s)}) = -581.0 \ kJ \ mol^{-1}$,$\Delta_{f}H^{\circ}(CO_{2(g)}) = -394.0 \ kJ \ mol^{-1}$
$S^{\circ}(SnO_{2(s)}) = 56.0 \ J \ K^{-1} \ mol^{-1}$,$S^{\circ}(Sn_{(s)}) = 52.0 \ J \ K^{-1} \ mol^{-1}$
$S^{\circ}(C_{(s)}) = 6.0 \ J \ K^{-1} \ mol^{-1}$,$S^{\circ}(CO_{2(g)}) = 210.0 \ J \ K^{-1} \ mol^{-1}$
Assume that the enthalpies and the entropies are temperature independent.

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