Sulphide ions react with sodium nitroprusside in a basic medium giving a coloured solution. In the reaction,the oxidation state of iron:

  • A
    Changes from $+2$ to $+4$
  • B
    Changes from $+3$ to $+2$
  • C
    Changes from $+2$ to $+3$
  • D
    Does not change

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$0.001 \ mol$ of $Co(NH_3)_5(NO_3)(SO_4)$ was passed through a cation exchanger. The acid coming out of it required $20 \ mL$ of $0.1 \ M$ $NaOH$ for neutralization. Hence,the complex is:

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Which statement is wrong?

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The correct option(s) about entropy $(S)$ is(are)
$[R =$ gas constant, $F =$ Faraday constant, $T =$ Temperature $]$
$(A)$ For the reaction, $M_{(s)} + 2H^{+}_{(aq)} \rightarrow H_{2(g)} + M^{2+}_{(aq)}$, if $\frac{dE_{cell}}{dT} = \frac{R}{F}$, then the entropy change of the reaction is $R$ (assume that entropy and internal energy changes in entropy and internal energy are temperature independent).
$(B)$ The cell reaction, $Pt_{(s)} \mid H_2(g, 1 \ bar) \mid H^{+}(aq, 0.01 \ M) \parallel H^{+}(aq, 0.1 \ M) \mid H_2(g, 1 \ bar) \mid Pt_{(s)}$, is an entropy driven process.
$(C)$ For racemization of an optically active compound, $\Delta S > 0$.
$(D)$ $\Delta S > 0$, for $[Ni(H_2O)_6]^{2+} + 3en \rightarrow [Ni(en)_3]^{2+} + 6H_2O$ (where $en =$ ethylenediamine).

Based on the provided reaction scheme,choose the incorrect statement:
$1. \text{Metal nitrate} \xrightarrow{\Delta} A + O_2$
$2. \text{Flame test of metal nitrate} \rightarrow \text{Golden Yellow Flame}$
$3. A + \text{Thiourea} \rightarrow \text{Solution } B$
$4. \text{Solution } B + FeCl_3 \rightarrow \text{Blood red colour complex}$

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Given below are two statements:
Statement $I$: Crystal Field Stabilization Energy $(CFSE)$ of $[Cr(H_2O)_6]^{2+}$ is greater than that of $[Mn(H_2O)_6]^{2+}$.
Statement $II$: Potassium ferricyanide has a greater spin-only magnetic moment than sodium ferrocyanide.
In the light of the above statements, choose the correct answer from the options given below:

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