The $[Fe(CN)_6]^{3-}$ complex ion

Which compound is formed when an excess of $KCN$ is added to an aqueous solution of copper sulphate?

The $IR$ stretching frequencies of free $CO$ and $CO$ in $[V(CO)_6]^-$,$[Cr(CO)_6]$ and $[Mn(CO)_6]^+$ are $2143 \, cm^{-1}$,$1860 \, cm^{-1}$,$2000 \, cm^{-1}$ and $2090 \, cm^{-1}$,respectively. Then the correct statement about metal carbonyls is:

Which of the following has the maximum molar conductivity?

The number of moles of $NH_{3}$ that must be added to $2 \, L$ of $0.80 \, M \, AgNO_{3}$ in order to reduce the concentration of $Ag^{+}$ ions to $5.0 \times 10^{-8} \, M$ ($K_{\text{formation}}$ for $[Ag(NH_{3})_{2}]^{+} = 1.0 \times 10^{8}$) is ...... . (Nearest integer)
[Assume no volume change on adding $NH_{3}$ ]

On adding an excess of $NH_3$ solution to $CuSO_4$ solution,the dark blue colour is due to the formation of which complex?