The $emf$ of the following cell $Mg|Mg^{2+}(0.01 \ M)||Sn^{2+}(0.1 \ M)|Sn$ at $298 \ K$ in $V$ is: (Given: $E^{\circ}_{Mg^{2+}|Mg} = -2.34 \ V, E^{\circ}_{Sn^{2+}|Sn} = -0.14 \ V$)

  • A
    $2.17$
  • B
    $2.23$
  • C
    $2.51$
  • D
    $2.45$

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At $298 \, K$,the standard reduction potential for $Cu^{2+}/Cu$ electrode is $0.34 \, V$.
Given: $K_{sp} \text{ of } Cu(OH)_2 = 1 \times 10^{-20}$
Take $\frac{2.303 RT}{F} = 0.059 \, V$
The reduction potential at $pH = 14$ for the above couple is $(-)x \times 10^{-2} \, V$. The value of $x$ is $........$.

The standard $EMF$ for the given cell reaction $Zn + Cu^{2+} \rightarrow Cu + Zn^{2+}$ is $1.10 \ V$ at $25^oC$. The $EMF$ for the cell reaction,when $0.1 \ M \ Cu^{2+}$ and $0.1 \ M \ Zn^{2+}$ solutions are used,at $25^oC$ is .......... $V$.

What will be the reduction potential of $Cu$ in an aqueous solution with $pH = 12$? Given that the $K_{sp}$ of $Cu(OH)_2$ is $1 \times 10^{-19}$ and $E^{\circ}_{Cu^{+2}/Cu} = 0.34 \ V$.

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The standard $emf$ for the cell reaction $Zn_{(s)} + Cu^{2+}_{(aq)} \rightarrow Zn^{2+}_{(aq)} + Cu_{(s)}$ is $1.10 \, V$ at $25 \, ^\circ C$. What will be the $emf$ of the cell when using $0.1 \, M \, Cu^{2+}$ and $0.1 \, M \, Zn^{2+}$ solutions (in $, V$)?

Calculate the equilibrium constant of the reaction,$Cu_{(s)} + 2 Ag^{+}_{(aq)} \longrightarrow Cu^{2+}_{(aq)} + 2 Ag_{(s)}$,given that for the reaction $E^{\circ}_{cell} = 0.46 \ V$.

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