The $pH$ of a buffer solution formed by mixing $30 \text{ mL}$ of $0.1 \text{ M } NH_4OH$ and $30 \text{ mL}$ of $1 \text{ M } NH_4Cl$ solutions is $8.6$. The $pK_b$ of $NH_4OH$ is

  • A
    $5.4$
  • B
    $4.4$
  • C
    $5.6$
  • D
    $4.2$

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For a $10 \, mL$ solution containing $0.1 \, M \, NH_4Cl$ and $0.01 \, M \, NH_4OH$,which of the following additions will not change the $pH$ of the solution?

$2 \ g$ acetic acid and $3 \ g$ sodium acetate are present in $100 \ mL$ aqueous solution. What will be the $pH$ of the solution if the ionisation constant of acetic acid is $1.8 \times 10^{-5}$?

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