The aqueous solution containing which one of the following ions will be colourless?

  • A
    $Sc^{3+}$
  • B
    $Fe^{2+}$
  • C
    $Ti^{3+}$
  • D
    $Mn^{2+}$ (Atomic number $Sc = 21, Fe = 26, Ti = 22, Mn = 25$)

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The correct order of decreasing second ionisation enthalpy of $Ti(22), V(23), Cr(24)$ and $Mn(25)$ is

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Why is the $E^{\Theta }$ value for the $Mn^{3+}/Mn^{2+}$ couple much more positive than that for $Cr^{3+}/Cr^{2+}$ or $Fe^{3+}/Fe^{2+}$? Explain.

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