The boiling points of methanol,water,and dimethyl ether are respectively $65\,^{\circ}C$,$100\,^{\circ}C$,and $-24.8\,^{\circ}C$ (note: dimethyl ether is a gas at room temperature). Which of the following best explains these wide variations in boiling point $(b.p.)$?

  • A
    The molecular mass increases from water $(18)$ to methanol $(32)$ to dimethyl ether $(46)$.
  • B
    The extent of $H$-bonding decreases from water to methanol,while it is absent in dimethyl ether.
  • C
    The extent of intramolecular $H$-bonding decreases from dimethyl ether to methanol to water.
  • D
    The density of water is $1.00\, g\, mL^{-1}$,methanol is $0.7914\, g\, mL^{-1}$,and that of dimethyl ether is $0.7137\, g\, mL^{-1}$.

Explore More

Similar Questions

Which of the following has the highest molar heat of vaporisation?

The correct statement/s about Hydrogen bonding is/are:
$A$. Hydrogen bonding exists when $H$ is covalently bonded to a highly electronegative atom.
$B$. Intermolecular $H$ bonding is present in $o$-nitrophenol.
$C$. Intramolecular $H$ bonding is present in $HF$.
$D$. The magnitude of $H$ bonding depends on the physical state of the compound.
$E$. $H$-bonding has a powerful effect on the structure and properties of compounds.
Choose the correct answer from the options given below:

$H_2O$ is a liquid while $H_2S$ is a gas due to:

Which of the following molecules can form hydrogen bonding with itself?

The hydrides of the first elements in groups $15-17$, namely $NH_3$, $H_2O$ and $HF$ respectively show abnormally high values for melting and boiling points. This is due to

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo