The bond angles b_1, b_2, b_3 in the above st | vedclass

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(D) The structure of $Al_2Cl_6$ (aluminum chloride dimer) consists of two $AlCl_4$ tetrahedra sharing an edge. In this structure,the terminal $Cl-Al-C

Vedclass · Accepted Answer

$118, 79, 101$

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(D) The structure of $Al_2Cl_6$ (aluminum chloride dimer) consists of two $AlCl_4$ tetrahedra sharing an edge. In this structure,the terminal $Cl-Al-Cl$ bond angle $(b_1)$ is approximately $118^{\circ}$. The bridging $Al-Cl-Al$ bond angle $(b_2)$ is approximately $79^{\circ}$. The $Cl-Al-Cl$ bond angle involving the bridging chlorine atoms $(b_3)$ is approximately $101^{\circ}$. Therefore,the values for $b_1, b_2, b_3$ are $118^{\circ}, 79^{\circ}, 101^{\circ}$ respectively.

The bond angles $b_1, b_2, b_3$ in the above structure of $Al_2Cl_6$ are respectively (in $^{\circ}$):

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