The dissociation constants for acetic acid and $HCN$ at $25\,^{\circ}C$ are $1.5 \times 10^{-5}$ and $4.5 \times 10^{-10}$ respectively. The equilibrium constant for the equilibrium $CN^{-} + CH_3COOH \rightleftharpoons HCN + CH_3COO^{-}$ would be

$A$ soft drink was bottled with a partial pressure of $CO_2$ of $3 \ bar$ over the liquid at room temperature. The partial pressure of $CO_2$ over the solution approaches a value of $30 \ bar$ when $44 \ g$ of $CO_2$ is dissolved in $1 \ kg$ of water at room temperature. The approximate $pH$ of the soft drink is............... $\times 10^{-1}$ (First dissociation constant of $H_2CO_3 = 4.0 \times 10^{-7}$; $\log 2 = 0.3$; density of the soft drink $= 1 \ g \ mL^{-1}$)

In which of the following mixed aqueous solutions, $pH = pK_{a}$ at equilibrium?
$(1)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 100 \ mL$ of $0.1 \ M \ CH_{3}COONa$
$(2)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 50 \ mL$ of $0.1 \ M \ NaOH$
$(3)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 100 \ mL$ of $0.1 \ M \ NaOH$
$(4)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 100 \ mL$ of $0.1 \ M \ NH_{3}$

At $25 \, ^\circ C$,the dissociation constant of pure water is equal to .......

What is ionic equilibrium? Discuss the relation of types of substances and ionic equilibrium in solution.

Which one of the following statements is correct?