The $emf$ of a $Daniel$ cell at $298 \ K$ is ${E_1}$ for the cell reaction $Zn|ZnSO_4(0.01 \ M)||CuSO_4(1.0 \ M)|Cu$. When the concentration of $ZnSO_4$ is $1.0 \ M$ and that of $CuSO_4$ is $0.01 \ M$,the $emf$ changes to ${E_2}$. What is the relationship between ${E_1}$ and ${E_2}$?

  • A
    ${E_2} = 0 \neq {E_1}$
  • B
    ${E_1} > {E_2}$
  • C
    ${E_1} < {E_2}$
  • D
    ${E_1} = {E_2}$

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Similar Questions

The potential of the cell for the reaction $M_{(s)} + 2H^{+}(1 \ M) \to H_2(1 \ atm) + M^{2+}(0.1 \ M)$ is $1.5 \ V$. The standard reduction potential for $M^{2+}/M_{(s)}$ couple is ............. $V$.

Consider the following electrochemical cell at $298 \ K$:
$Pt | HSnO_2^-(aq) | Sn(OH)_6^{2-}(aq) || Bi_2O_3(s) | Bi(s)$.
If the reaction quotient at a given time is $10^6$, then the cell $EMF$ $(E_{\text{cell}})$ is . . . . . . $\times 10^{-1} \ V$ (Nearest integer).
Given the standard half-cell reduction potential as
$E^0_{Bi_2O_3/Bi, OH^-} = -0.44 \ V$ and
$E^0_{Sn(OH)_6^{2-}/HSnO_2^-, OH^-} = -0.90 \ V$.

The pressure of hydrogen gas is increased from $1 \, atm$ to $100 \, atm$ keeping the $[H^+]$ constant at $1 \, M$. The potential of the hydrogen half-cell at $25 \, ^\circ C$ will be .......... $V$.

Find the $emf$ of the following cell reaction,given $E^0_{Cr^{3+}/Cr} = -0.74 \ V$ and $E^0_{Fe^{2+}/Fe} = -0.44 \ V$ at $25^{\circ} C$ for the cell: $Cr \ | \ Cr^{3+}(0.1 \ M) \ || \ Fe^{2+}(0.01 \ M) \ | \ Fe$. (in $V$)

The standard $emf$ of a galvanic cell involving $2$ moles of electrons in its redox reaction is $0.59 \ V$. The equilibrium constant for the redox reaction of the cell is

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