The enthalpy of combustion of methane at $25\,^{\circ}C$ is $890\,kJ$. The heat liberated when $3.2\,g$ of methane is burnt in air is.....$kJ$

Assertion : The increase in internal energy $(\Delta E)$ for the vaporization of one mole of water at $1 \ atm$ and $373 \ K$ is zero.
Reason : For all isothermal processes,$\Delta E = 0$.

The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in the figure. Which of the following statement$(s)$ is (are) correct?
$(A)$ $T_1 = T_2$
$(B)$ $T_3 > T_1$
$(C)$ $W_{\text{isothermal}} > W_{\text{adiabatic}}$
$(D)$ $\Delta U_{\text{isothermal}} > \Delta U_{\text{adiabatic}}$

The heat of reaction for $C_2H_2 + H_2 \rightarrow C_2H_4$ is given by the following data:
$(i) \Delta H_f^o \text{ of } H_2O_{(\ell)} = -68.3 \ K \ cal \ mol^{-1}$
$(ii) \Delta H_{comb}^o \text{ of } C_2H_2 = -337.2 \ K \ cal \ mol^{-1}$
$(iii) \Delta H_{comb}^o \text{ of } C_2H_4 = -363.7 \ K \ cal \ mol^{-1}$

What is the value of $\Delta S_{\text{total}}$ for the following reaction at $300 \ K$:
$Fe_{2}O_{3(s)} + 3CO_{(g)} \longrightarrow 2Fe_{(s)} + 3CO_{2(g)}$
$\Delta H^{\circ} = -25 \ kJ, \Delta S^{\circ} = 15 \ J \ K^{-1}$ (in $J \ K^{-1}$)

The quantity of heat (in $J$) required to raise the temperature of $1.0 \, kg$ of ethanol from $293.45 \, K$ to the boiling point and then change the liquid to vapor at that temperature is closest to
[Given,boiling point of ethanol $351.45 \, K$. Specific heat capacity of liquid ethanol $2.44 \, J \, g^{-1} \, K^{-1}$. Latent heat of vaporisation of ethanol $855 \, J \, g^{-1}$ ]