The experimentally determined molar mass of a non-volatile solute, $BaCl_2$, in water by Cottrell's method, is

  • A
    equal to the calculated molar mass
  • B
    more than the calculated molar mass
  • C
    less than the calculated molar mass
  • D
    double of the calculated molar mass

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The molecular weight of benzoic acid in benzene as determined by the depression in freezing point method corresponds to:

If $0.1 \ M$ solution of $NaCl$ is isotonic with $1.1 \ w \%$ urea solution, the degree of ionisation of $NaCl$ is $($Molar masses of urea and $NaCl$ are $60 \ g \ mol^{-1}$ and $58.5 \ g \ mol^{-1}$, respectively.$)$

$HA_{(aq)} \rightleftharpoons H^{+}_{(aq)} + A^{-}_{(aq)}$
The freezing point depression of a $0.1 \ m$ aqueous solution of a monobasic weak acid $HA$ is $0.20^{\circ} C$. The dissociation constant for the acid is. Given: $K_{f}(H_2O) = 1.8 \ K \ kg \ mol^{-1}$,molality $\equiv$ molarity.

When $0.0106 \text{ mole}$ of acetic acid is dissolved in $1 \text{ kg}$ of water, the observed freezing point depression is $0.0205 \text{ K}$. If the calculated freezing point depression is $0.0197 \text{ K}$, the Van't Hoff factor $(i)$ and the degree of dissociation $(\alpha)$ of acetic acid are respectively:

$A$ $0.5\%$ solution of potassium chloride was found to freeze at $-0.24^{\circ} C$. The percentage dissociation of potassium chloride is .... (Nearest integer)
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