The first ionization enthalpy values (in $kJ\,mol^{-1}$) of group $13$ elements are :
$B$ $801$
$Al$ $577$
$Ga$ $579$
$In$ $558$
$Tl$ $589$

How would you explain this deviation from the general trend?

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(N/A) On moving down a group,ionization enthalpy generally decreases due to an increase in the atomic size and shielding effect.
Thus,on moving down group $13$,ionization enthalpy decreases from $B$ to $Al$.
However,$Ga$ has a higher ionization enthalpy than $Al$ because $Ga$ follows the $d$-block elements.
The shielding provided by $d$-electrons is poor,which leads to a higher effective nuclear charge experienced by the valence electrons in $Ga$.
Moving from $Ga$ to $In$,the ionization enthalpy decreases due to the increase in atomic size.
Finally,from $In$ to $Tl$,the ionization enthalpy increases because $Tl$ follows the $4f$ and $5d$ orbitals.
The poor shielding effect of $f$ and $d$ electrons results in a higher effective nuclear charge,holding the valence electron more strongly.

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