The following bimolecular elimination reaction $(E_2)$ is carried out with different halogen leaving groups. The per cent yield of the two products ($2$-hexene and $1$-hexene) for each leaving group is listed below.
Leaving groupConj. Acid $pK_a$$\%$-yield of $2$-hexene$\%$-yield of $1$-hexene
$X = I$$-10$$81\%$$19\%$
$X = Br$$-9$$72\%$$28\%$
$X = Cl$$-7$$67\%$$33\%$
$X = F$$3.2$$30\%$$70\%$

Which of the following statement$(s)$ is/are true concerning this series of $E_2$ reactions?

  • A
    Based on the $pK_a$ values of the conjugate acid,$I^{-}$ is the best leaving group and $F^{-}$ is the poorest leaving group.
  • B
    When $I^{-}$,$Br^{-}$,and $Cl^{-}$ are used as leaving groups,Zaitsev's rule is followed.
  • C
    $F^{-}$ is the strongest base (and therefore the poorest leaving group) and the transition state for reaction with fluoride as the leaving group has the least double bond character.
  • D
    $a$,$b$,and $c$ are true.

Explore More

Similar Questions

Which one of the following is more readily hydrolysed by $S_{N}1$ mechanism?

$ . . . . . . $ compound is slowly oxidized by air in the presence of light to an extremely poisonous gas, carbonyl chloride.

$A$ $(C_{4}H_{8}Cl_{2})$ $\xrightarrow{\text{Hydrolysis at } 373 \text{ K}}$ $B$ $(C_{4}H_{8}O)$
$B$ reacts with hydroxylamine but does not give Tollen's test. Identify $A$ and $B$.

The major product obtained in the following reaction is $C_2H_5ONa + (CH_3)_3C-Cl \rightarrow$

Which of the following phrases are not correctly associated with $S_N1$ reaction?
$(1)$ Rearrangement is possible
$(2)$ Rate is affected by polarity of solvent
$(3)$ The strength of the nucleophile is important in determining rate
$(4)$ The reactivity series is tertiary $>$ secondary $>$ primary
$(5)$ Proceeds with complete inversion of configuration

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo