The following lists contain reactions and their corresponding equilibrium constants at different temperatures:
List-$I$ (Reaction) List-$II$ $(K_p)$
$2 SO_{2(g)} + O_{2(g)} \rightleftharpoons 2 SO_{3(g)}$ at $298 \ K$ $4.0 \times 10^{24}$
$2 SO_{2(g)} + O_{2(g)} \rightleftharpoons 2 SO_{3(g)}$ at $700 \ K$ $3.0 \times 10^{4}$
$N_2O_{4(g)} \rightleftharpoons 2 NO_{2(g)}$ at $298 \ K$ $0.98$
$N_2O_{4(g)} \rightleftharpoons 2 NO_{2(g)}$ at $500 \ K$ $1700$

If $\Delta H_1^0$ and $\Delta H_2^0$ are the standard enthalpies for the reactions $2 SO_{2(g)} + O_{2(g)} \rightleftharpoons 2 SO_{3(g)}$ and $N_2O_{4(g)} \rightleftharpoons 2 NO_{2(g)}$ respectively, then:

  • A
    Both $\Delta H_1^0$ and $\Delta H_2^0$ are negative
  • B
    Both $\Delta H_1^0$ and $\Delta H_2^0$ are positive
  • C
    $\Delta H_1^0$ is negative and $\Delta H_2^0$ is positive
  • D
    $\Delta H_1^0$ is positive and $\Delta H_2^0$ is negative

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