The formation of the oxide ion,$O^{2-}_{(g)}$,from oxygen atom requires first an exothermic and then an endothermic step as shown below:
$O_{(g)} + e^- \to O^{-}_{(g)} ; \Delta_f H^{\Theta} = -141 \ kJ \ mol^{-1}$
$O^{-}_{(g)} + e^- \to O^{2-}_{(g)} ; \Delta_f H^{\Theta} = +780 \ kJ \ mol^{-1}$
Thus,the process of formation of $O^{2-}$ in gas phase is unfavourable even though $O^{2-}$ is isoelectronic with neon. It is due to the fact that,

  • A
    Oxygen is more electronegative
  • B
    Addition of electron in oxygen results in larger size of the ion
  • C
    Electron repulsion outweighs the stability gained by achieving noble gas configuration
  • D
    $O^{-}$ ion has comparatively smaller size than oxygen atom

Explore More

Similar Questions

The increasing order of electron affinity for the given electronic configurations of elements is:
$I$. $1s^2 \ 2s^2 \ 2p^6 \ 3s^2 \ 3p^5$ $(Cl)$
$II$. $1s^2 \ 2s^2 \ 2p^3$ $(N)$
$III$. $1s^2 \ 2s^2 \ 2p^5$ $(F)$
$IV$. $1s^2 \ 2s^2 \ 2p^6 \ 3s^2 \ 3p^1$ $(Al)$

Difficult
View Solution

Which of the following statements is correct?

Electronic configurations of four elements $A, B, C$ and $D$ are given below :
$(A)$ $1s^2 2s^2 2p^6$
$(B)$ $1s^2 2s^2 2p^4$
$(C)$ $1s^2 2s^2 2p^6 3s^1$
$(D)$ $1s^2 2s^2 2p^5$
Which of the following is the correct order of increasing tendency to gain electron :

Difficult
View Solution

In which of the following,elements are arranged in the correct order of their electron gain enthalpies?

Nitrogen has lower electron affinity than its preceding element carbon because

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo