The half-life values for two different first-order reactions $A$ and $B$ are $75 \ min$ and $2.5 \ h$ respectively. What is the ratio of their rate constants $\frac{k_A}{k_B}$?

The following results are obtained in one pseudo first order reaction:

Time $(s)$	$0$	$30$	$60$	$90$
Concentration $(mol \ L^{-1})$	$0.551$	$0.312$	$0.173$	$0.085$

$(a)$ Calculate the average rate of reaction between $30$ and $60$ seconds.
$(b)$ Calculate the rate constant $(k)$ of this first order reaction.

Identify $True$ $(T)$ and $False$ $(F)$ statements of the following for a first order reaction $R \rightarrow P$.
$I. \log \frac{[R]}{[R]_0} = -\frac{kt}{2.303}$
$II. \log \frac{[R]}{[R]_0} = \frac{kt}{2.303}$

When methyl acetate is hydrolyzed in $0.05 \, M$ $HCl$,the reaction occurs as follows: $CH_3COOCH_3 + H_2O \rightarrow CH_3COOH + CH_3OH$. $A$ $25 \, mL$ sample of the reaction mixture is taken at different time intervals,added to ice to stop the reaction,and then titrated with $0.05 \, M$ $NaOH$ solution. Prove that the reaction is first order using the data provided below:

Time (minute)	$0$	$20$	$75$	$120$	$\infty$
Volume of $0.05 \, M$ $NaOH$ ($V_t$ in $mL$)	$24.40$	$25.82$	$29.35$	$31.75$	$47.50$

For the thermal decomposition of $N_2O_{5(g)}$ at constant volume,the following table can be formed for the reaction mentioned below:
$2N_2O_{5(g)} \rightarrow 2N_2O_{4(g)} + O_{2(g)}$

$S.NO$	$Time/s$	Total pressure $(atm)$
$1.$	$0$	$0.6$
$2.$	$100$	$X$

$X = . . . . . . \times 10^{-3} \ atm$ [nearest integer]
Given: Rate constant for the reaction is $4.606 \times 10^{-2} \ s^{-1}$.

Which of the following is a correct statement for a first-order reaction?