The heat of combustion of carbon is $-393.5 \ kJ / mol$. The heat released upon the formation of $35.2 \ g$ of $CO_{2}$ from carbon and oxygen gas is

At $298 \ K$,the enthalpy of fusion of a solid $(X)$ is $2.8 \ kJ \ mol^{-1}$ and the enthalpy of vaporisation of the liquid $(X)$ is $98.2 \ kJ \ mol^{-1}$. The enthalpy of sublimation of the substance $(X)$ in $kJ \ mol^{-1}$ is $.....$ (in nearest integer).

Given the following data:

Reaction	Energy Change (in $kJ$)
$Li_{(s)} \to Li_{(g)}$	$161$
$Li_{(g)} \to Li^{+}_{(g)}$	$520$
$\frac{1}{2} F_{2(g)} \to F_{(g)}$	$77$
$F_{(g)} + e^- \to F^{-}_{(g)}$	(Electron gain enthalpy)
$Li^{+}_{(g)} + F^{-}_{(g)} \to LiF_{(s)}$	$-1047$
$Li_{(s)} + \frac{1}{2} F_{2(g)} \to LiF_{(s)}$	$-617$

Based on the data provided,the value of electron gain enthalpy of fluorine would be $kJ\ mol^{-1}$.

The heat of atomization of methane and ethane are $360 \ kJ/mol$ and $620 \ kJ/mol,$ respectively. The longest wavelength of light capable of breaking the $C-C$ bond is (Avogadro number $= 6.02 \times 10^{23},$ $h = 6.62 \times 10^{-34} \ J \cdot s$)

The standard heat of formation,in $kcal / mol$ of $Ba^{2+}$ is
[Given : standard heat of formation of $SO_4^{2-}$ ion $(aq) = -216 \ kcal / mol$,
Standard heat of crystallisation of $BaSO_{4(s)} = -4.5 \ kcal / mol$,standard heat of formation of $BaSO_{4(s)} = -349 \ kcal / mol$]

The enthalpies of formation of $Al_{2}O_{3}$ and $Cr_{2}O_{3}$ are $-1596 \ kJ$ and $-1134 \ kJ$ respectively. $\Delta H$ for the reaction $2Al + Cr_{2}O_{3} \to 2Cr + Al_{2}O_{3}$ is.......$kJ$