The initial rate for a first order reaction is $0.6932 \times 10^{-2} \ mol \ L^{-1} \ min^{-1}$ and the initial concentration of the reactant is $0.1 \ M$. Then $t_{1/2}$ is equal to ...... $min$.

Identify True $(T)$ and False $(F)$ statements for the first order reaction $R \rightarrow P$ given below:
$I. \ k = \frac{1}{t} \ln \frac{[R]_0}{[R]}$
$II. \ k = \frac{1}{t} \ln \frac{[R]}{[R]_0}$

Hydrolysis of methyl acetate in aqueous solution has been studied by titrating the liberated acetic acid against sodium hydroxide. The concentration of the ester at different times is given below:

Time $(t)$ $(\min)$	$0$	$30$	$60$	$90$
Conc. of ester $(C)$ $(M)$	$0.850$	$0.800$	$0.754$	$0.710$

Show that it follows a pseudo first order reaction as the concentration of $H_{2}O$ remains nearly constant $(55 \ mol \ L^{-1})$ during the course of the reaction. What is the value of $k^{\prime}$ in this reaction?

The value of the velocity constant for a first-order reaction is $3.46 \times 10^{-3} \ min^{-1}$. The time for half-change is ........ $min$.

What is the half-life of a first-order reaction if the rate constant is $4.2 \times 10^{-2} \text{ day}^{-1}$ (in $\text{ days}$)?

Calculate the rate constant of a first-order reaction if the concentration of the reactant decreases by $90 \%$ in $30 \ minutes$.