The intermediate during the addition of HCl t | vedclass

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Question

(B) The addition of $HCl$ to propene follows Markovnikov's rule,even in the presence of peroxide.Peroxide effect (Kharasch effect) is only applicable

Vedclass · Accepted Answer

$CH_3-CH^{+}-CH_3$

Vedclass · Answer

(B) The addition of $HCl$ to propene follows Markovnikov's rule,even in the presence of peroxide.Peroxide effect (Kharasch effect) is only applicable to $HBr$ and not to $HCl$ or $HI$.In the reaction,the electrophile $H^+$ attacks the double bond to form the more stable secondary carbocation,$CH_3-CH^{+}-CH_3$,as the reaction intermediate.Therefore,the correct intermediate is $CH_3-CH^{+}-CH_3$.

The intermediate during the addition of $HCl$ to propene in the presence of peroxide is

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