The major product $Z$ formed in the following sequence of reactions is:

$p$-Toluidine reacts with benzene diazonium chloride to form a compound,which on boiling with $aq. H_2SO_4$ gives ........ products.

$90 \ g$ of ethylamine on reaction with methyl chloride produces a tertiary amine as the exclusive product. The amount of methyl chloride required is:
$[\text{Given atomic masses in amu}: H=1, C=12, N=14, Cl=35.5]$ (in $g$)

Compound $D$ is

Product $D$ is:-

Match List-$I$ with List-$II$ :

List-$I$	List-$II$
$a$. Gabriel synthesis	$i$. Benzaldehyde
$b$. Kolbe synthesis	$ii$. Ethers
$c$. Williamson synthesis	$iii$. Primary amines
$d$. Etard reaction	$iv$. Salicylic acid

Choose the correct answer from the options given below :