The partial pressures of $CH_3OH$,$CO$ and $H_2$ in the equilibrium mixture for the reaction $CO(g) + 2H_2(g) \rightleftharpoons CH_3OH(g)$ at $427 \ ^oC$ are $2.0 \ atm$,$1.0 \ atm$ and $0.1 \ atm$ respectively. The value of $K_P$ for the decomposition of $CH_3OH$ to $CO$ and $H_2$ is:

  • A
    $1 \times 10^2 \ atm^2$
  • B
    $2 \times 10^2 \ atm^{-2}$
  • C
    $50 \ atm^2$
  • D
    $5 \times 10^{-3} \ atm^2$

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For the reaction $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$,the equilibrium constant $K_p = 41$ at $400 \ K$. Calculate $K_c$ for the following reactions at $400 \ K$:
$(a)$ $2N_{2(g)} + 6H_{2(g)} \rightleftharpoons 4NH_{3(g)}$
$(b)$ $2NH_{3(g)} \rightleftharpoons N_{2(g)} + 3H_{2(g)}$
$(c)$ $\frac{1}{2}N_{2(g)} + \frac{3}{2}H_{2(g)} \rightleftharpoons NH_{3(g)}$

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