The principal buffer present in human blood is:

The $pK_a$ of an equimolar mixture of sodium acetate and acetic acid is $4.74$. What is the $pH$ of the solution?

The ratio of volumes of $CH_3COOH$ $0.1 \ N$ to $CH_3COONa$ $0.1 \ N$ required to prepare a buffer solution of $pH$ $5.74$ is (Given, $pK_a$ of $CH_3COOH$ is $4.74$)

What is the $pH$ of a solution containing $50 \ mL$ each of $0.1 \ M$ sodium acetate and $0.01 \ M$ acetic acid (in $.5$)? $(pK_{a} \ CH_3COOH = 4.50)$

$A$ solution is prepared by mixing $0.01 \ mol$ each of $H_2CO_3$,$NaHCO_3$,$Na_2CO_3$,and $NaOH$ in $100 \ mL$ of water. The $pH$ of the resulting solution is. . . . . . .
[Given : $pK_{a1}$ and $pK_{a2}$ of $H_2CO_3$ are $6.37$ and $10.32$,respectively; $\log 2=0.30$ ]

At $25 \, ^\circ C$,the $K_a$ for $HCN$ is $5 \times 10^{-10}$. What volume (in $mL$) of $5 \, M \, KCN$ solution must be added to $10 \, mL$ of $2 \, M \, HCN$ solution to maintain a constant $pH$ of $9$?