The product$(s)$ formed when toluene is reacted with $Cl_2$ in the presence of $Fe$ in the dark is/are:

  • A
    $o-$chlorotoluene and $p-$chlorotoluene
  • B
    benzyl chloride
  • C
    benzal chloride
  • D
    benzotrichloride

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Similar Questions

$STATEMENT-1$: Bromobenzene upon reaction with $Br_2 / Fe$ gives $1,4$-dibromobenzene as the major product.
$STATEMENT-2$: In bromobenzene,the inductive effect of the bromo group is more dominant than the mesomeric effect in directing the incoming electrophile.

The product $(A)$ of the given reaction is:

Given below are two statements:
Statement $I$: Benzene is nitrated to give nitrobenzene, which on further treatment with $CH_{3}COCl / AlCl_{3}$ will give the product shown in the image.
Statement $II$: $NO_{2}$ group is a $m$-directing and deactivating group.
In the light of the above statements, choose the most appropriate answer:

Arrange the following set of compounds in order of their decreasing relative reactivity with an electrophile,$E^{+}$:
$(a)$ Chlorobenzene,$2,4-$dinitrochlorobenzene,$p-$nitrochlorobenzene
$(b)$ Toluene,$p-CH_3-C_6H_4-NO_2$,$p-O_2N-C_6H_4-NO_2$

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Why do aryl halides undergo electrophilic substitution reactions at $o-$ and $p-$positions? Why are they less reactive than benzene?

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