The rate constant of the reaction,$2 H_2O_2 \rightarrow 2 H_2O + O_2$ is $3 \times 10^{-3} \ min^{-1}$. At what concentration of $H_2O_2$ will the rate of reaction be $2 \times 10^{-4} \ M \ s^{-1}$?

  • A
    $6.67 \times 10^{-3} \ M$
  • B
    $4 \ M$
  • C
    $0.08 \ M$
  • D
    $2 \ M$

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The reaction of formation of phosgene from $CO$ and $Cl_2$ is $CO + Cl_2 \to COCl_2.$ The proposed mechanism is
$(i)$ $Cl_2 \,\underset{k_2}{\overset{k_1}{\longleftrightarrow}}\, 2Cl$
$(ii)$ $Cl + CO \,\underset{k_4}{\overset{k_3}{\longleftrightarrow}}\, COCl$
$(iii)$ $COCl + Cl_2 \xrightarrow{k_5} COCl_2 + Cl$ (slow)
Find the correct expression of rate law.

Rate of reaction for $2X + Y \rightarrow 3W + Z$ is $1.2 \times 10^{-4} \ mol \ dm^{-3} \ sec^{-1}$ when $[X] = [Y] = 0.6 \ mol \ dm^{-3}$. Calculate the value of the rate constant if the reaction is first order in $X$ and zero order in $Y$.

For a given reaction $t_{1/2} = \frac{1}{Ka}$. The order of the reaction is

The following data is given for the reaction between $A$ and $B$:
$S.NO.$$[A] \ mol \ L^{-1}$$[B] \ mol \ L^{-1}$$Rate \ mol \ L^{-1} \ sec^{-1}$
$I$$1 \times 10^{-2}$$2 \times 10^{-2}$$2 \times 10^{-4}$
$II$$2 \times 10^{-2}$$2 \times 10^{-2}$$4 \times 10^{-4}$
$III$$2 \times 10^{-2}$$4 \times 10^{-2}$$8 \times 10^{-4}$

Which of the following are correct statements?
$(a)$ Rate constant of the reaction is $1 \ mol^{-1} \ L \ sec^{-1}$.
$(b)$ Rate law of the reaction is $k[A][B]$.
$(c)$ Rate of reaction increases four times on doubling the concentration of both the reactants.

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For the non-stoichiometric reaction $2A + B \to C + D$,the following kinetic data were obtained in three separate experiments,all at $298 \ K$.
Initial Conc. $(A)$ Initial Conc. $(B)$ Initial rate of formation of $C \ (mol \ L^{-1} \ s^{-1})$
$0.1 \ M$ $0.1 \ M$ $1.2 \times 10^{-3}$
$0.1 \ M$ $0.2 \ M$ $1.2 \times 10^{-3}$
$0.2 \ M$ $0.1 \ M$ $2.4 \times 10^{-3}$

For the reaction,the rate of formation of $C$ will be:

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